SOLUTION

In chemistry, a solution is a homogeneous mixture composed of only one phase, In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. The solvent does the dissolving. The solution more or less takes on the characteristics of the solvent including its phase, and the solvent is commonly the major fraction of the mixture. The concentration of a solute in a solution is a measure of how much of that solute is dissolved in the solvent.

Types of solutions

Homogeneous means that the components of the mixture form a single phase. The properties of the mixture (such as concentration, temperature, and density) can be uniformly distributed through the volume but only in absence of diffusion phenomena or after their completion. Usually the substance present in the greatest amount is considered the solvent. Solvents can be gases, liquids, or solids. One or more components present in the solution other than the solvent are called solutes: The solution has the same physical state as the solvent.

Gas

If the solvent is a gas, only gases are dissolved under a given set of conditions. An example of a gaseous solution is air (oxygen and other gases dissolved in nitrogen). Since interactions between molecules play almost no role, dilute gases form rather trivial solutions. In part of the literature, they are not even classified as solutions, but addressed as mixtures.

Liquid

If the solvent is a liquid, then gases, liquids, and solids can be dissolved. Here are some examples:

1. Gas in liquid:

· Oxygen in water.

· Carbon dioxide in water is a less simple example, because the solution is accompanied by a chemical reaction (formation of ions). Note also that the visible bubbles in carbonated water are not the dissolved gas, but only an effervescence of carbon dioxide that has come out of solution; the dissolved gas itself is not visible since it is dissolved on a molecular level.

2. Liquid in liquid:

· The mixing of two or more substances of the same chemistry but different concentrations to form a constant.(Homogenization of solutions)

· Alcoholic beverages are basically solutions of ethanol in water.

3. Solid in liquid:

· Sucrose (table sugar) in water

· Sodium chloride or any other salt in water forms an electrolyte: when dissolving, salt dissociates into ions.

Counter examples are provided by liquid mixtures that are not homogeneous: colloids, suspensions, emulsions are not considered solutions.

Body fluids are examples for complex liquid solutions, containing many different solutes. They are electrolytes since they contain solute ions such as potassium. Furthermore, they contain solute molecules like sugar and urea. Oxygen and carbon dioxide are also essential components of blood chemistry, where significant changes in their concentrations may be a sign of illness or injury.

Solid

If the solvent is a solid, then gases, liquids, and solids can be dissolved.

1. Gas in solid:

• Hydrogen dissolves rather well in metals, especially in palladium; this is studied as means of hydrogen storage.

2. Liquid in solid:

• mercury in gold, forming an amalgam

• hexane in paraffin wax

3. Solid in solid:

• steel, basically a solution of carbon atoms in a crystalline matrix of iron atoms.

• alloys like bronze and many others.

• polymers containing plasticizers.

Properties

The physical properties of compounds such as melting point and boiling point change when other compounds are added. Together they are called colligative properties. There are several ways to quantify the amount of one compound dissolved in the other compounds collectively called concentration. Examples include molarity, mole fraction, and parts per million (PPM).

The properties of ideal solutions can be calculated by the linear combination of the properties of its components. If both solute and solvent exist in equal quantities (such as in a 50% ethanol, 50% water solution), the concepts of "solute" and "solvent" become less relevant, but the substance that is more often used as a solvent is normally designated as the solvent (in this example, water).

Date: 2015-01-29; view: 1772