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Colorful neon signs are

used for advertising throughout the world.

Welding of aluminumis

carried out under a "blan­ket" of argon gas. The inert argon does not react with the hot metal, nor does it allow oxygen in the air to oxidize it.


 


Fact entries

Heliumwas discovered in the mineral clevite in 1895 by the Scottish chemist Wil­liam Ramsay (1852-1916). It was named after the Greek helios, meaning sun, be­cause it was first detected in the sun's spectrum. At. no. 2; at. mass 4.0026; m.p. -272.2" C; b.p. -268.9° C.


Neonwas also discovered by Ramsay, with Morris Travers (1872-1961), in 1898 in impure argon from air. Its name derives from the Greek neos, meaning new. At. no. 10; at. mass 20.179; m.p. -248.67° C; b.p. - 246.048° C.


Argonwas isolated from air in 1894 by Ramsay and Lord Rayleigh (1842-1919). Its name comes from the Greek argos, meaning inac­tive. At. no. 18; at. mass 39.948; m.p. -189.2° C; b.p. -185.7° C.

Kryptonwas discovered by Ramsay and Travers in 1898.


It is named after the Greek kryptos, meaning hidden. At. no. 36; at. mass 83.80; m.p. -156.6° C; b.p. 152.3° C.

Xenon,from the Greek word for strange, was also discovered by Ramsay and Travers in 1898. At. no. 54; at. mass 131.29; m.p. -111.9°C; b.p. -107.1° C.


Radonwas discovered by the German chemist Frie-drichDorn (1848-1916) in 1900. It was later isolated by Ramsay. It is formed by the radioactive decay of radium, after which it is named. It is itself radioactive. At. no. 86; at. mass (the most stable iso­tope) 222; m.p. -71° C; b.p. -61.8° C.



 

   
Be    
9.0128    
 
Mg    
24.305 3B 4B
Ca Sc Ti
? 40.08 44.9559 47.88
Sr Y Zr
87.62 88.9059 91.224
Ba La Hf
137.33 138.906 178.49
Ra Ac  
226.025 227.028  

The scandium group

makes up Croup 3B of the periodic table. It includes the lanthanides (elements 57 to 71) and the actinides (ele­ments 89 to 103).

Many phosphorscontain lanthanide compounds. These phosphors produce the colors on television screens and on VDU dis­plays for computer graph­ics.


The scandium group and the lanthanides

Scandium (Sc), yttrium (Y), lanthanum (La), and actinium (Ac) are the four elements that form Group 3B of the periodic table. However, lan­thanum and actinium have their own series of related elements, known as the lanthanides and actinides. These form separate groups within the periodic classification. The lantha­nides are included in this article. The actinides are the subject of the next one.

In some respects, the Group 3B elements resemble those of Group 3A: boron, alumi­num, gallium, indium, and thallium. The re­semblance is particularly strong with scan­dium, whose chemistry is much like that of aluminum. Scandium, yttrium, and lanthanum oxidize (combine with oxygen) readily when exposed to air. These elements also react with water to release hydrogen.



Scandium

Scandium is a soft, silvery-white metal. It is quite common, there being almost as much of the element in the earth's crust as there is of arsenic and almost twice as much as there is


of boron. There are few rich mineral sources of scandium. It usually occurs mixed with other lanthanides in the minerals thortveitite and wiikite. Sometimes, it is found in tin and tungsten ores. In all, it is found in over 800 minerals, although only in very small amounts. Scandium is not separated easily from other elements. It is separated using a special and difficult process involving an exchange of ions (electrically-charged atoms) of the element while in solution. Scandium is employed mostly in high-intensity lights. Astronomers have also found that some stars contain much scandium.

Yttrium

Yttrium is a heavy, silvery-white metal that re­sembles lanthanum and the lanthanides. It is found in nearly all minerals that contain the rare earths. It is obtained commercially from monazite sand. Yttrium has various uses, espe­cially in the electronics industry. A compound called yttrium oxide is used in color television screens as the basis of the color red. The same compound is also used to make a kind of crys­tal called a garnet. One type of garnet is used as a filter in radar. Another type serves as an imitation diamond. Yttrium is also used in la­sers and in manufacturing certain ceramics, chemicals, and glass. It finds use as a catalyst and in the making of various alloys.

Lanthanum

Lanthanum is a soft and pliable silver-white metal. It is found together with the lanthanides in monazite, bastnasite, and other minerals. It is also produced during nuclear fission (the splitting of atoms), which involves uranium, thorium, and plutonium. Lanthanum finds use in different alloys, especially in making lighter flints. It is also used as a catalyst and in the glass industry, in which it is employed in cam­era lenses and carbon-arc searchlights.

The rare earths

The lanthanides are also known as the rare earth elements because they were found at first only rarely, and then only as oxides (com-



Monaziteis a phosphate mineral that is the principal source of cerium and other lanthanides, and of thorium. It occurs in beach sands along the southwestern coast of Pakistan.


Major groups of elements: The scandium group and lanthanides 59



bined with oxygen). These oxides resemble calcium, magnesium, and aluminum oxides, which are sometimes known as the common earths. By modern standards, however, they are not rare. Some of them are even produced on a large scale. Even the scarcest—thulium-is as common as bismuth and occurs in more abundance than arsenic, mercury, cadmium, or selenium.

Apart from promethium, the lanthanides al­ways occur together—most commonly in the mineral monazite, a dense, dark sand that con­tains mixtures of lanthanide phosphates. These are mixtures of a variety of the rare earths combined with phosphorus. The lanthanides are also found in combination with other non-metallic elements in the form of carbonates (with carbon), silicates (with silicon), and fluo­rides (with fluorine). Lanthanum, cerium, pra­seodymium, and neodymium make up to 90 per cent of all mineral deposits of lanthanides. Yttrium and the heavier elements of the group make up the rest. Promethium does not occur naturally. Several artificial isotopes have been made, sometimes as a product of nuclear fis­sion. But these are all short-lived.

Until the end of World War II, the extrac­tion of rare earth elements was a long, compli­cated, and costly process. There are two proc­esses in use today, the ion-exchange and the solvent extraction processes. These chemical processes have made possible a rapid separa­tion that gives highly pure, low-cost rare earths.

True rare earths, after separation from their oxides, are silver-colored metals. These sepa­rated rare earths are used in lasers, magnets, lamps, television screens, and some kinds of X-ray equipment. Unseparated rare earths help make metals, such as aluminum and magne­sium, stronger. Another type of rare earth alloy (called misch metal) is combined with iron to make flints for cigarette lighters. Rare earth elements are also used in motion-picture projectors and in the production of various petroleum and synthetic products.


-i—i—i—i—i—i—i—i—i—r-

La3' Ce31' Pr3' Na- Pm3' Sm3* Eu3' Gd3- IV Dy3' Ho-" Er34 Tm3* Yb3' Lu3*

Lanthanide ions

The lanthanide contrac­tionrefers to the steady de­crease in the size of the lan­thanide ions along the series from lanthanum to lu-tetium (rather than the ex­pected increase).

 

Element Symbol Atomic number Atomic weight Discovery date Discoverer
Cerium Ce 140.12 W. von Hisinger, Jons Berzelius, and Martin Klaproth
Praseodymium Pr 140.907 Carl von Welsbach
Neodymium Nd 144.24 Carl von Welsbach
Promethium Pm 145.00 J.A. Marinsky, L.E. Glendenin, and CD. Coryell
Samarium Sm 150.35 Lecoq de Boisbaudran
Europium Eu 151.96 Eugene Demarcay
Gadolinium Gd 157.25 J. de Marignac
Terbium Tb 158.924 Carl Mosander
Dysprosium Dy 162.50 Lecoq de Boisbaudran
Holmium Ho 164.930 j.L Soret
Erbium Er 167.26 Carl Mosander
Thulium Tm 168.934 PerTheodor Cleve
Ytterbium Yb 173.04 J. de Marignac and George Urbain
Lutetium Lu 174.97 George Urbain
           

Fact entries


Scandiumwas one of the "missing" elements pre­dicted by Dmitri Mende­leev. It was discovered in 1879 by the Swedish chem­ist Lars Nilson (1840-1899). He named it after Scandia, the Latin name for Scandina­via. At. no. 21; at. mass 44.9559; m.p. 1539° C; b.p. 2832' C.


Yttriumis one of several el­ements named after the town of Ytterby in Sweden. It was discovered by the Swedish chemist Carl Gustav Mosander (1797-1858) in 1843 in the mineral yttria. At. no. 39; at. mass 88.9059; m.p. 1522±8° C; b.p. 3338° C.


Lanthanumwas discov­ered in 1839 as an impurity in cerium by Carl Mo­sander. Its name derives from the Greek lanthano, which means to be hidden. At. no. 57; at. mass 138.906; m.p. about 920° C; b.p. about 3469° C.


Lanthanides(rare earth el­ements) are listed in the above table, which gives brief details of the atomic number and weight and the discovery of each of them.

Actiniumis described in the following article.



Date: 2015-12-11; view: 857


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