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The first transition series

The beaches of New Zea­land'swestern coast are re­markable for their black sands. These sands contain ilmenite (a source of iron and titanium) in commer­cially exploitable amounts.

These metals—titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), co­balt (Co), and nickel (Ni)—are all of major in­dustrial importance. They are important in the making of ceramics and ceramic glazes and in various high-performance alloys, which are used to make special steel, such as steel for tools. These elements and their compounds are also used as catalysts (substances that speed up chemical reactions) in the produc­tion of certain chemicals and synthetic materi­als.

Titanium is a lightweight, silver-gray metal.


It is widely distributed in the earth's crust, being the ninth most abundant element. How­ever, it is never found in a pure state, usually occurring in the minerals ilmenite or rutile. Ti­tanium resists corrosion and rust better than stainless steel. It can be drawn into fine wire and is not affected by strong acids. It with­stands temperatures up to about 427° C (800° F.). It also has a higher strength-weight ratio than steel. However, it is difficult and ex­pensive to extract titanium from the ores in which it is found. For this reason, the metal is not widely used, being restricted to aircraft and jet engines. It is also used in the manufac­ture of white paints, plastics, paper, and por­celain enamels.

Vanadium is a silver-white metal that is found in very small quantities throughout the earth's crust. It is used mostly in the manufac­ture of "ferrovanadium," an alloy of iron and 50 to 70 per cent vanadium. This strong, rust-re­sistant alloy is used in the production of steel parts for airplanes, cars, and locomotives, and for making high-speed cutting tools. It is also suitable for use in nuclear reactors. Vanadium is an important trace element in the human body.

Chromium is a glossy, gray, fairly soft metal. It is found in nature usually combined with ox­ygen and iron in a mineral called chromite. Sometimes called chrome, the metal does not easily corrode and becomes very shiny when polished. For these reasons, chromium is often used to plate metals used for car bump­ers, door handles, and decorative trim. Stain­less steel contains at least 10 per cent chro­mium. Stainless steel, because it doesn't easily rust, is often used for making eating utensils and kitchen equipment. Chromium-steel alloys are used to make ball bearings, safes, armor plating for ships and military vehicles, and the cutting edges of high-speed machine tools.

Manganese is a brittle, silver-gray metal, plentiful throughout the earth's crust, though not always accessible. The leading producers of the metal are the Soviet Union, South Af­rica, and Brazil. Manganese is employed mainly in special steels used in making heavy-duty machinery, safes, electromagnets (for radar transmitters and computer storage units), and stainless steel. It is used in the man­ufacture of dry cell batteries, dyes, paints, fer­tilizers, and compounds for water purification. Manganese is a trace element required by all plants and animals, including human beings.



Iron, a silvery-white metal in its pure state, is found in nature combined with other ele­ments in iron ores. It is very abundant throughout the earth's crust. Iron is by far the most commonly used structural metal. It is often combined with other metals of this se­ries into steel alloys. All kinds of steel can be grouped as carbon steel (the most common), alloy steel, stainless steel, and tool steel. Iron is also indispensable to the human body. The average adult male body contains one-eighth ounce (3.5 grams). About 65 per cent is found in hemoglobin, which carries oxygen from the lungs to the various parts of the body. Iron is also needed for the proper functioning of cells, muscles, and other tissues.

Cobalt is a hard, silver-white metal that is also magnetic, like iron and nickel. It is rela­tively rare in the earth's crust. In the making of



Major groups of elements: The transition metals 41


 
 


Oxygen Scrap iron Limestone
Molten, impure iron tapped from blast furnace and poured into ladles

Molten, impure iron in ladles taken to basic oxygen furnace for making into steel

Iron ore

Concentrated ore heated with limestone, coke and air in blast furnace, producing molten, impure iron

Ore

pulverized and concentrated to increase proportion of iron

Blast Furnace

Waste gases (CO + C02) out

Outer steel casing

fcaC03 + SiO, 4 i CaSi03 + CO,, C + C02 -2CO ! and i 2C + 02 -. 2C0 I Fe203 + 3CO -2Fe + 3C0P

Inner lining of refractory bricks

Iron ore (Fe203 + impurities mainly Si02), coke (C) and limestone (CaC03) in

Hot air in

Moften slag Molten iron

Molten slag (CaSi03) out

Molten, impure^ ->

iron out

steel alloys, cobalt's ability to withstand high temperatures makes it ideal for use in gas tur­bines, jet engines, and other equipment that operates at high temperatures. Cobalt is also alloyed with aluminum and nickel or iron for use as magnets in radios, TV sets, and other devices. An isotope of cobalt—cobalt 60— is used in the treatment of cancer.

Nickel is a malleable white metal that is magnetic, can be polished to a high gloss, and does not tarnish easily or rust. The leading nickel-producers are the Soviet Union, Can­ada, and Australia. Nickel's resistance to corro­sion makes it invaluable in making storage bat­teries. Nickel-iron alloys are used to make armor plate and machine parts. Invar (an alloy


 

Molten steel poured from ladles into ingots, or into a rolling mill to make steel bars
Oxygen in

Steel ingots or bars remelted for casting into molds, or other­wise fabricated into finished products

Basic Oxygen Furnace

Molten iron, scrap iron and limestone in

Inner lining of refractory bricks

Outer steel casing

Tap-hole for molten steel

of nickel, iron, and other metals) is used for meter scales and pendulum rods, because it expands very little with temperature changes. Nickel-silver is an alloy used in tableware. The U.S. five-cent piece, also called a nickel, is made of copper and nickel.

Second and third transition series: 1

The eight elements that form the first halves of the second and third transition series can be treated as one group. They are zirconium (Zr), niobium (Nb), molybdenum (Mo), technetium (Tc), hafnium (Hf), tantalum (Ta), tungsten (W), and rhenium (Re). These elements vary in abundance from the relatively rare to com-


Z_

Molten iron, scrap iron limestone and oxygen heated in oxygen furnace, producing refined, basic steel

Molten steel poured into ladles and I alloying metals added \ (if desired) to produce specific alloy steels

The main stages in the commercial production of iron and its chief alloy, steel,are illustrated in the flow diagram (above). The key stages are the reduction of the iron ore to impure iron in a blast furnace (far left), and the refining of this impure iron in an oxygen furnace to produce basic steel (left). The iron from the blast furnace contains up to 5 per cent of impurities, which make the metal brit­tle. These are removed by oxidation at a high tempera­ture in the oxygen furnace. This process is so efficient that scrap iron can be added for direct conversion to steel. The basic steel pro­duced consists of iron with less than one per cent car­bon. Other metals may then be added to make alloy steels.


 


Fact entries

Titaniumwas discovered by William Gregor of Eng­land in 1791. It was named after the Titans in Greek my­thology by Martin Klaproth of Germany in 1795. At. no. 22; at. mass 47.88; m.p. 1667+10" C;b.p. 3287'C.

Vanadiumwas discovered in 1830 by the Swedish chemist Nils Sefstrom (1787-1845). He named it after Vanadis, the Scandinavian goddess of beauty. At. no. 23; at. mass 50.9415; m.p. 1890+10° C;b.p. about 3380' C.


Chromiumwas discovered in 1797 by the French chem­ist Louis Nicolas Vauquelin (1763-1829). Its name comes from the Greek chromos, meaning color. Many of its compounds are highly col­ored. At. no. 24; at. mass 51.996; m.p. 1900° C; b.p. 2690° C.

Manganesewas recog­nized as an element in 1774 by the Swedish chemist Karl Scheele (1744-1786). It was isolated in the same year by the Swedish chemist Johan Gahn (1745-1818). Its name is


probably a corruption of Magnesia, the name of a re­gion of ancient Greece. At. no. 25; at. mass 54.938; m.p. 1244±3° C; b.p. 1962° C.

Ironhas been known since 4000 B.C., although it was not in wide use until about 1000 B.C. Its chemical sym­bol, Fe, derives from the Latin name for the element, ferrum. At. no. 26; at. mass 55.847; m.p. 1535° C; b.p. 3000° C

Cobaltwas isolated in about 1735 by the Swedish


chemist Georg Brandt (1694-1768). However, its blue-col­ored compounds had been known centuries earlier. Its name derives from the Ger­man kobold, meaning gob­lin. At. no. 27; at. mass 58.9332; m.p. 1495° C; b.p. about 2870° C.

Nickelwas isolated in 1751 from an ore containing nickel and arsenic. It was isolated by the Swedish chemist Axel Cronstedt (1722-1765). The ore he used was once called (in German) kupfernickel, from which


the element later derived its name. At. no. 28; at. mass 58.69; m.p. 1555° C; b.p. 2837° C


42 Major groups of elements: The transition metals II


 
 


3B 4B 5B 6B 7B f   >\ 1B
Sc Ti V Cr Mn Fe Co Ni Cu
44.9559 47.88 50.9415 51.996 54.938 55.847 58.9332 58.69 63.546
4?
v Zr Nb Mo Tc Ru Rh Pd Ag
88.9059 91.224 92.9064 95.94 (98) 101.07 102.906 106.42 107.868
| La Hf Ta w Re Os lr Pt Au
138.906 178.49 180.948 183.85 186.207 190.2 192.22 195.08 196.967
   
Ac                
227.028                
 

The block of transition metalsfrom zirconium to technetium and from haf­nium to rhenium exhibit similar properties and can be treated as a single group. All are rare in nature—apart from technetium, which does not occur naturally at all. As a group, they tend to have only a few, highly spe­cialized uses. Zirconium (found in the gemstone zir­con), tungsten, and molyb­denum (both used in vari­ous alloys) are probably the most familiar.


plete nonoccurrence in nature. All are metals, with considerable similarities in their proper­ties, notably in their vertical relationships in the periodic table. Zirconium and hafnium, for example, have generally similar metallic prop­erties and compounds, as do niobium and tan­talum, and molybdenum and tungsten. All these elements form many complex com­pounds.

Zirconium is a gray-white metal that is widely distributed in the earth's crust. It is found in the minerals baddeleyite and zircon, from which it is extracted by a process that uses molten magnesium. If a zircon crystal is large, it may be used for jewelry. Otherwise, zirconium is very valuable for use in atomic re­actors. Because it has a high resistance to cor­rosion and does not readily absorb neutrons, it is used to make the cores of the reactors and to coat the uranium fuel elements. Zirconium is also very resistant to high temperatures and is useful to the ceramics industry. It is used for making laboratory crucibles (melting pots for metals) and for lining furnaces. As a powdered metal, zirconium is used in smokeless flash powders, blasting caps, and fireworks. Be­cause it is a very strong metal, zirconium is used to make tools such as rock drills. Some of the best superconducting metals are


niobium-zirconium alloys, containing 20 to 40 per cent zirconium.

Niobium, also called columbium, is a soft metal that varies in color from silver-white to gray, it is usually found in nature combined with the metal tantalum. Niobium is used in making high-strength steels for use in oil and gas pipelines, drill bits, and turbine blades. It is also used in the cores of certain nuclear re­actors for increased strength and resistance to high temperatures.

Molybdenum is a hard, silver-white metal. Most of the world's supply comes from Colo­rado. Chile and Canada also produce the metal. When combined with certain other met­als, molybdenum increases strength, tough­ness, and resistance to heat and chemicals. It is used in armor plate, tool steels, and high-strength steels for aircraft engines and missile parts. Molybdenum compounds are used in high-temperature lubricants and in the refin­ing of petroleum.

Technetium occurs in nature in very small quantities. It was the first artificially created el­ement and is now obtained as a by-product from atomic fission. All its isotopes are unsta­ble and radioactive. They have no significant use except for one form, which is used in ra­diotherapy of thyroid disorders.

Hafnium is a silver-colored metal that is al­ways found in combination with zirconium. Hafnium absorbs neutrons better than most metals and is used to control the rate of reac­tions in the reactors of nuclear submarines. It is also used in cutting tools, aircraft engine parts, and some gas-filled and incandescent lamps.

Tantalum is a rare metal that occurs in na- | ture with the element niobium in the minerals columbite and tantalite. It is also obtained as a by-product in the extraction of certain kinds of tin. Like niobium, tantalum is used in high-strength steels and nuclear reactors. It is also used in the electronics industry, in the produc­tion of camera lenses, and in medicine for bone repair and internal stitching.

Tungsten is a moderately hard, silver-white



Molybdenumis used as an alloying agent in armor plat­ing which basically consists of alloy steel. Molybdenum is one of the most effective elements for increasing the hardenability and toughness of steel. In addition, molyb­denum is highly corrosion resistant. It is also unusual in retaining its strength and hardness at extremely high temperatures. These prop­erties make the metal itself and its alloys very useful for industrial chemical equip­ment.


Major groups of elements: The transition metals II 43




metal. It occurs in nature in the minerals scheelite and wolframite. It is also called wol­fram. Tungsten has the highest melting point of all metals. It is therefore used in equipment that must withstand very high temperatures. It is made into heating filaments for vacuum tubes used in radios, TV's, and other elec­tronic equipment. It is also used to make fila­ments for electric lights and contact points for the ignition systems of cars and trucks. Like molybdenum, tungsten is also used for high-strength steels that remain strong at high tem­peratures. It is used in the tips of high-speed cutting tools and in mining and petroleum drills. Compounds of tungsten are used in flu­orescent lamps.

Rhenium is a rare, costly, silvery-white metal that can withstand high temperatures. To make electrical equipment that is heat-re­sistant, it is mixed with platinum or tungsten. It is also used in making fine wires called fila­ments for use in light instruments, such as mass spectrographs.

Second and third transition series: II

Six of the transition metals are known as the precious metals. They are ruthenium (Ru), rho­dium (Rh), palladium (Pd), osmium (Os), iridium (Ir), and platinum (Pt). They occupy positions in the second halves of the second and third transition series. Although differing in atomic weight, the physical and chemical properties of each element are similar to those of the ver­tical member directly below or above. All the dements in this group are rare, but tend to occur together, being obtained and separated only with difficulty. Most of these metals come from Canada, South Africa, and the Soviet Union, often as minor components of copper ores.

The platinum group elements are all high-density metals with generally similar proper­ties. They resist forming compounds with oxy­gen. They have high melting points. They can form extremely hard alloys, for example, for electrical contacts and the tips of pen nibs. In


Zirconium, hafnium, and niobiumare used in nu­clear reactors, such as the one shown. Zirconium and niobium, or sometimes an alloy of the two, are used to clad the fuel elements. They allow neutrons to pass through them easily. In con­trast, hafnium is used in some nuclear reactors for its high neutron absorption. This property makes it valu­able as a control-rod mate­rial.

Tungsten carbide(WC) is

one of the most important compounds of tungsten be­cause of its extreme hard­ness. This makes it useful for the cutting edges of ma­chine tools.


 


Fact entries

Zirconiumwas identified in 1789 by the German chemist Martin Klaproth (1743-1817). It was not iso­lated until 1824, by the Swedish chemist Jons Ber-zelius (1779-1848). Its name derives from that of its main source, the semiprecious mineral zircon. At. no. 40; at. mass 91.224; m.p. 1857° C; b.p. 4200° C.

Niobiumwas first discov­ered in 1801 by the British chemist Charles Hatchett (1765-1847). He named it co-lumbium, a name still used occasionally with the chemi­cal symbol Cb. The element was rediscovered in 1844 by the German chemist Hein-rich Rose (1795-1864). He distinguished it from tanta-


lum and named it niobium, after Niobe, the daughter of Tantalus in Greek mythol­ogy. At. no. 41; at. mass 92.9064; m.p. 2468+10° C; b.p. 4742° C.

Molybdenumwas identi­fied in 1778 by the Swedish chemist Karl Scheele (1744-1786). It was isolated in 1782 by another Swedish chem­ist, Peter Hjelm. Its name de­rives from the Greek molyb-dos, meaning lead, because it was once thought to be a lead ore. At. no. 42; at. mass 95.94; m.p. 2617° C; b.p. about 4612° C.

Technetiumwas the first element to be produced ar­tificially. Its name comes from the Greek technetos,


meaning artificial. It was dis­covered in 1937 by the Ital­ian scientists Carlo Perrier and Emilio Segre. At. no. 43; at. mass (of longest-lived isotope) 98; m.p. about 2200° C; b.p. about 4850° C.

Hafniumwas discovered in 1923 by the Dutch physicist Dirk Coster (1889-1950) and the Hungarian chemist Georg von Hevesy (1885-1966). Hafnium is derived from Hafnia, the Latin name for Copenhagen (Denmark), where the element was dis­covered. At. no. 72; at. mass 178.49; m.p. 2227° C; b.p. 4602° C.

Tantalumwas discovered in 1802 by the Swedish chemist Anders Ekeberg


(1767-1813). He named it after Tantalus in Greek my­thology because its isola­tion had proved to be such a tantalizing task. At. no. 73; at. mass 180.948; m.p. 2996° C; b.p. 5425+100° C

Tungstenderives its name from the Swedish words tung, meaning heavy, and sten, meaning stone. It was first isolated in 1783 by the Spanish scientist Fausto de Elhuyar and his brother Juan. They obtained the metal from the mineral wolframite (iron and manga­nese tungstate). Hence, the element's alternative name of wolfram and its chemical symbol W. At. no. 74; at. mass 183.85; m.p. about 3400° C; b.p. about 5600° C.


Rheniumwas predicted to exist by the Russian chemist Dmitri Mendeleev (1834-1907) in 1869. It was not dis­covered until 1925, by the German chemists Walter Noddack (1896-1960), Ida Tacke (1896-1978), and Otto Berg, who named it after the River Rhine. At. no. 75; at. mass 186.207; m.p. 3180° C; b.p. about 5627° C.


44 Major groups of elements: The transition metals III


:ir 4B 5B OR 7B r ------------- ■*•---------- > 1B
Sc Ti V Cr Mn Fe Co Ni Cu
44.9559 47.88 50.9415 51.996 54.938 55.847 58.9332 58.69 63.546
Y Zr Nb Mo Tc Ru Rh Pd Ag
88 9059 91.224 92.9064 95.94 (98) 101.07 102.906 106.42 107.B68
La Hf Ta w Re Os lr Pt Au
138.906 178.49 180 948 183.85 186.207 190.2 '192.22 195.08 196.967
   
Ac                
227.028                

The block of transition metals from ruthenium to palladium and from os­mium to platinumare

commonly called the plati­num group metals. They usually occur together in nature, although they are rare. They are usually diffi­cult to extract and separate from each other.


the periodic table, elements combining with second row metals form less stable com­pounds than those of the same element com­bined with third row metals. Compounds of second row metals are, therefore, more chem­ically reactive.

Ruthenium is a hard and brittle metal. It is sometimes combined with platinum and palla­dium in order to increase hardness. An alloy of platinum and 10 per cent ruthenium is used for making electrical contacts in certain types of small generators employed in aircraft.

Rhodium is a silver-white metal that is very resistant to corrosion and can be polished to a high gloss. It is used as a finish for mirrors, searchlights, and jewelry. Usually alloyed with platinum, rhodium is used in high-tempera­ture electrical connections and in aircraft tur­bine engines. The same alloy is used as a cata­lyst (to speed up chemical reactions) in the manufacture of nitric acid for fertilizers and ex­plosives. A platinum-rhodium alloy is also


used in the production of high-octane gaso­line and aromatic compounds.

Palladium is a silver-white metal, soft and shiny. Because it resembles platinum, palla­dium is often used in its place. The metal is also harder, lighter, and less expensive than platinum. Palladium is very malleable. It can be flattened into sheets or drawn into wire. Mixed with gold, it is used to make "white gold" jew­elry. It is also used in making surgical instru­ments. A certain type of palladium, called pal­ladium black, is important in a process called hydrogenation. This is a process that improves the quality of oils and is used in making gaso­line. Palladium is also combined with platinum into devices that reduce the amount of pollu­tion given off by car engines.

Osmium, in its pure form, is a fine, black powder or a hard, blue-gray metal. It is twice as heavy as lead. Of all the metals in the plati­num group, osmium reacts most readily with the air. Especially when heated over 93° C, os­mium forms a poisonous vapor that can dam­age the skin or even the eyes and the lungs. Osmium is used in the making of electric light filaments, tips for pen points, and phonograph needles.

Iridium is a hard, brittle, white metal. It is more resistant to corrosion than any known metal. It is also one of the hardest metals. Being too brittle by itself, however, it is most often used to increase the hardness of plati­num. Platinum-iridium alloys are used in mak­ing jewelry, fountain pen tips, bearings for navigational compasses, and small crucibles (containers for heating chemicals). The alloys are also used for certain other equipment that operates at high temperatures or around cor­rosive substances.

Platinum is a silver-white metal that is one



The most recent tech­nique for extracting the platinum group metals

(PGMs) is based on solvent extraction. Part of a refinery in which this process is car­ried out is shown in the photograph. The details of the solvent extraction of PGMs are closely-guarded secrets. Basically, however, a mixture of the metals in aqueous solution is mixed with an organic reagent. This reagent does not mix with water. Further, it reacts with only one of the metals, thereby removing it from the aqueous phase and into the organic phase. The metal-reagent solution is then processed to extract the metal in pure form. This process is repeated to ob­tain each of the metals in turn.


Major groups of elements: The transition metals III





The sealin the photograph (left) is made of platinum, a precious metal used exten­sively in jewelry and other such ornamental objects. Platinum has a brilliant silver-white appearance and is very malleable. It is resist­ant to corrosion by acids, being attacked only by caus­tic alkalis.

The tips of pen nibsIright) are often made of osmium-iridium alloy, a substance that is very hard and has ex­cellent corrosion resistance. Almost all osmium pro­duced is used in alloys be­cause the pure metal is brit­tle, even at high temperatures.


of the heaviest substances known. A specific quantity of platinum weighs 21 times as much as an equal amount of water. Platinum is more valuable than gold. Its strength, hardness, color, and freedom from tarnish make it ideal for gem settings. Yet it is soft enough to be etched with delicate designs. Platinum is more malleable than other metals; only gold and sil­ver are easier to shape. As already discussed, platinum has many uses in alloys with other metals of the platinum group. The Interna­tional Standard kilogram of mass is made from an alloy of 90 per cent platinum and 10 per cent iridium, because the metal is so stable. In medicine, compounds of platinum are used in chemotherapy to treat cancerous tumors.


Fact entries

Rutheniumwas isolated in 1844 by the Russian chemist Karl Klaus (1796-1864). Its name comes from the medi­eval Latin Ruthenia for a re­gion in central Europe now part of the Soviet Union. At. no. 44; at. mass 101.07; m.p. about 2250° C; b.p. about 3900" C.

Rhodiumwas isolated in 1803 by the British chemist William Wollaston (1766-1828). He derived its name from the Creek rhodon, meaning rose, because of


the red color of many of the element's compounds in so­lution. At. no. 45; at. mass 102.906; m.p. 1966+3° C; b.p. 3727±100°C.

Palladiumwas isolated in

1803 by William Wollaston.
It was named after Pallas, a
recently discovered aster­
oid. At. no. 46; at. mass

106.42; m.p. 1552° C; b.p. 2940° C.

Osmium was discovered in

1804 by the British chemist
Smithson Tennant (1761 -


1815). He named it for the unpleasant smell of some of its compounds. The Greek osme means odor. At. no. 76; at. mass 190.2; m.p. 2700° C; b.p. about 5300° C.

Iridiumwas discovered in 1804 by Smithson Tennant. He derived its name from the Latin iris, meaning rain­bow. Its compounds exhibit a variety of colors. At. no. 77; at. mass 192.22; m.p. 2410° C; b.p. 4130° C.


Platinumderives its name from the Spanish platina, meaning "little silver," be­cause of its resemblance to the latter metal. It was origi­nally discovered by the Ital­ian Julius Scaliger in 1557. It was reliably reported in South America in 1735 by the Spanish mathematician Antonio de Ulloa. It was then brought to Europe in 1741 by the British metallur­gist Charles Wood. At. no. 78; at. mass 195.08; m.p. 1772° C; b.p. about 3827° C.


 

4A 5A 6A
c N o
12.011 14.0067 15.9994
Si P s
28 0855 30.9738 32.06
Ge As Se
72.59 74.9216
Sn Sb Te
118.71 121.75 127 6
Pb Bi Po
207.2 208.98 (209)

Nitrogenis the first ele­ment in Group 5A of the pe­riodic table. It is by far the most abundant gaseous ele­ment on earth, constituting more than three-quarters of the volume of the atmos­phere.

The nitrogen cycleis a

complex series of transfor­mations. Atmospheric nitro­gen is converted by living organisms and lightning into inorganic and organic nitrogen compounds. They are then converted back to gaseous nitrogen. The prin­cipal stages in the cycle are illustrated in the diagram below.


Nitrogen

Nitrogen (N), the first element in Group 5A of the periodic table, is a colorless, odorless, and tasteless gas. It is essential to all living matter. Nitrogen makes up approximately 78 per cent by volume of the earth's atmosphere. It is also found in plant and animal proteins. There are few inorganic or mineral deposits containing nitrogen because most of its compounds dis­solve in water. Deposits of sodium nitrate (Chile saltpeter) are found in Chile and in some other areas with a dry climate. These have been mined for use as a fertilizer and to make explosives.

Nitrogen can also be made artificially. Air is cooled until it liquefies and then cooled even further to the boiling point of nitrogen, — 195.8° C. The nitrogen is then removed.

Most nitrogen is used for the production of fertilizers from ammonia (a compound of ni­trogen and hydrogen) or nitric acid (a com­pound of nitrogen, hydrogen, and oxygen). The gas itself is also used in the chemical, electrical, and metals industries. In the food in­dustry, it prevents spoilage by mold. Liquid ni­trogen is easily prepared and is used as a re­frigerant

The nitrogen cycle

On the average, nitrogen makes up about 16 per cent of animal and vegetable proteins. The other 84 per cent consists of carbon, hydro­gen, oxygen, and sulfur. Only a few simple or­ganisms are able to use nitrogen directly from the air for the manufacture of the proteins they require for growth and tissue maintenance. Plants, in general, take nitrogen from the soil in the form of nitrates, nitrites, and ammo­nium salts—all compounds containing nitro­gen. Animals and humans absorb most of the nitrogen they require from eating plants or other animals. There is, therefore, a vital rela­tionship between plants, animals, the soil, and the nitrogen in the air. This interdependence


is known as the nitrogen cycle.

Complex environmental, biological, and chemical processes cycle nitrogen out of the air and into soil and water. From there, nitro­gen is absorbed by the living tissue in plants, animals, and humans. When living tissue dies, bacteria release the nitrogen back into the earth and into the air.

Nitrogen finds its way to the soil in rain water as dilute nitric acid and nitrous acid, two different combinations of hydrogen, nitrogen, and oxygen. These two compounds are formed in the atmosphere when lightning causes nitrogen and oxygen to react and com­bine with rain water. Falling to the earth, nitric acid and nitrous acid then react with certain chemicals in the soil called bases to form ni­trates and nitrites. Plants can use these nitrogen-containing compounds to form pro­teins. Certain types of bacteria and algae (called nitrogen-fixing bacteria and algae) also take nitrogen directly from the air and convert it into ammonia (a compound of nitrogen and hydrogen), which can then be used by plants.

Bacteria also play an important role in re­leasing the nitrogen from dead organic matter. Decaying plant tissue releases ammonia to the soil, which builds up there as ammonium salts. More bacteria (called nitrifying bacteria) con­vert these salts into nitrates and nitrites, which can be used once more by plants for the pro­duction of protein. Much of the nitrogen in an­imal protein is also returned to the soil when animals die and decay. Plant protein ingested by animals is excreted mainly as urea. This substance, when returned to the soil, can react with water to give carbon dioxide and ammo­nia.

Not all this combined, or "fixed," nitrogen is held in the soil. Some of it is broken down back to nitrogen by bacteria (called denitrify­ing bacteria) and returned as gaseous nitrogen to the atmosphere.


Date: 2015-12-11; view: 368


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Silicon and germanium | Ammonia and hydrazine
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