Functional Groups

Functional groups are atoms or small groups of atoms (two to four) that exhibit a characteristic reactivity when treated with certain reagents. A particular functional group will almost always display its characteristic chemical behavior when it is present in a compound. Because of their importance in understanding organic chemistry, functional groups have characteristic names that often carry over in the naming of individual compounds incorporating specific groups. In the following table the atoms of each functional group are colored red and the characteristic IUPAC nomenclature suffix that denotes some (but not all) functional groups is also colored.

Functional Group Tables

Exclusively Carbon Functional Groups

Group Formula	Class Name	Specific Example	IUPAC Name	Common Name
	Alkene	H2C=CH2	Ethene	Ethylene
Alkyne	HC≡CH	Ethyne	Acetylene
Arene	C6H6	Benzene	Benzene

Functional Groups with Single Bonds to Heteroatoms

Group Formula	Class Name	Specific Example	IUPAC Name	Common Name
	Halide	H3C-I	Iodomethane	Methyl iodide
Alcohol	CH3CH2OH	Ethanol	Ethyl alcohol
Ether	CH3CH2OCH2CH3	Diethyl ether	Ether
	Amine	H3C-NH2	Aminomethane	Methylamine
Nitro Compound	H3C-NO2	Nitromethane
Thiol	H3C-SH	Methanethiol	Methyl mercaptan
Sulfide	H3C-S-CH3	Dimethyl sulfide

Functional Groups with Multiple Bonds to Heteroatoms

Group Formula	Class Name	Specific Example	IUPAC Name	Common Name
	Nitrile	H3C-CN	Ethanenitrile	Acetonitrile
Aldehyde	H3CCHO	Ethanal	Acetaldehyde
Ketone	H3CCOCH3	Propanone	Acetone
Carboxylic Acid	H3CCO2H	Ethanoic Acid	Acetic acid
Ester	H3CCO2CH2CH3	Ethyl ethanoate	Ethyl acetate
Acid Halide	H3CCOCl	Ethanoyl chloride	Acetyl chloride
Amide	H3CCON(CH3)2	N,N-Dimethylethanamide	N,N-Dimethylacetamide
Acid Anhydride	(H3CCO)2O	Ethanoic anhydride	Acetic anhydride

Date: 2015-01-29; view: 944