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Industrial production and use of oxygen

Oxygen is made in very large quantities by the fractional distillation of liquid air. In this proc­ess, air is filtered and dried and carbon diox­ide removed. The resulting gas mixture—con­taining nitrogen, oxygen, and the rare gases (mainly argon)—is compressed and cooled until it liquefies. The liquefied air is then dis­tilled in a column. The liquid becomes richer and richer in oxygen, and the gas distilled off richer and richer in nitrogen. Liquid oxygen, which is pale blue in color, is removed 99.5 percent pure. It is transferred to steel pres­sure vessels for further use.

Oxygen can also be made by the electroly­sis of water. In this process, an electric current passed through water yields oxygen at the anode (the positive electrode at one end of the current) and hydrogen at the cathode (the neg­ative electrode at the other end). Both of these gases can be collected in this manner and stored.

Commercially, oxygen is used in the pro­duction of steel, the manufacture of chemicals from natural gas, and the formation of impor­tant industrial oxygen compounds, such as ox-irane and sodium peroxide. Oxygen is mixed with fuel in welding torches, producing a very hot flame with a temperature close to 6000° F. (3300° 0. LOX (liquid oxygen) can be used to make rocket fuel and blasting explosives. In both cases, LOX has to be mixed with liquid fuels. For example, to make rocket fuel, either kerosene or liquid hydrogen can be used.

Ozone

Ozone is a gas like ordinary oxygen, but it has a garliclike odor and very different chemical properties. A molecule of ozone is made up of three atoms of oxygen. A molecule of ordinary oxygen is made up of only two atoms. Ozone is found in its highest concentration at a height of 19 miles (30 kilometers) above the earth's surface. This so-called ozone layer is of vital importance in protecting life on earth from too much exposure to the sun's ultravio­let radiation, which harms living tissue. About 95 to 99 per cent of this radiation is blocked by the ozone layer. Ozone is also found in smaller amounts in the lower atmosphere, where it contributes to air pollution, being a compo­nent of smog.

Ozone is produced naturally when radia­tion from the sun strikes oxygen in the earth's upper atmosphere, converting some of it into ozone. It is also produced during lightning


storms, when electricity might convert oxygen into ozone.

Commercially, an "ozonizer" uses electric discharges to convert oxygen into ozone. The ozone can then be used in water purification processes or as a bleach in making waxes, oils, and fabrics.

Recent testing of the ozone layer has dem­onstrated that waste gases from industry and from aerosol sprays are damaging it. As a re­sult, steps are being taken by the U.S. govern­ment and other governments to control the use of certain pollutants that are causing the gradual breakdown of the ozone layer.


The commercial prepara­tion of oxygeninvolves the liquefaction of air under pressure. Liquid air is then distilled to remove nitrogen and argon and other rare gases, leaving liquid oxy­gen.



Fishes"breathe" the oxygen in water. Fresh water con­tains about 3 per cent of dis­solved oxygen. This is re­moved in a fish's gills and passed to the animal's bloodstream.


 


Fact entries

Oxygenwas discovered in 1774 independently by two chemists, Karl Scheele (1742-1786) in Sweden and Joseph Priestly (1733-1804) in England. They obtained the gas by heating mercuric oxide. But it was the French chemist Antoine Lavoisier (1743-1794) who correctly


explained the role of oxygen in combustion. He also coined the name oxygen from Greek words meaning acid-maker. He wrongly be­lieved that all acids contain oxygen. At. no. 8; at. mass 15.9994; m.p. -118.8° C; b.p. -182.962" C.


Oxidescan be classified into three main types: acidic, basic, and neutral. Acidic oxides react with water to form acids. Exam­ples include carbon dioxide, which forms carbonic acid, and sulfur trioxide, which forms sulfuric acid. Basic ox­ides form bases with water.


An example is sodium oxide, which forms sodium hydroxide. Neutral oxides, such as nitrous oxide and water, are neither acidic nor basic. Acids and bases are discussed more fully in the article "Key chemical reac­tions."


Ozonewas discovered in 1840 by the German chemist Christian Friedrich Schonbein. Pure ozone is a pale blue gas. At. mass 47.998.


5A 6A 7A
7 . 9 -f
N F
14-0067 15.9994 18.9984
15 : 17 !
P s CI
30.9738 32.06 35.453 ,
As Se Br
74:9216 78.96 79.904
Sb Te I
127.6 126 905
Bi Po At
208.98 (209) (210)

Sulfur to poloniumfollow oxygen to fill the remainder of Group 6A of the periodic table. Tellurium is unusual in having a higher atomic mass than its right-hand neighbor (iodine).

The Frasch methodis an

ingenious process of min­ing sulfur from deep under the ground. The sulfur oc­curs in a layer mixed with calcite (calcium carbonate). It is reached by means of a bore hole. Three concentric pipes are sunk down the hole. Water superheated to 311"F. (155° C) and under pressure is pumped down the outer pipe. Compressed air is forced down the inner one. The hot water melts the sulfur, which accumulates at the end of the pipes. A frothy mixture of sulfur, air, and water then passes up the middle pipe to the sur­face. There, it is run off to set in large molds. More than 80 per cent of the world's sulfur is obtained this way in Texas and Louisi­ana.


Sulfur to polonium

The elements sulfur (S), selenium (Se), tellu­rium (Te), and polonium (Po) make up, with ox­ygen, Group 6A of the periodic table. From sulfur to polonium, the elements are chemi­cally very similar, even though there is a defi­nite gradation of properties down the group. Oxygen has different properties from the rest—primarily because it combines so readily with other elements. It is also a gas, whereas the others are solids. Oxygen is discussed in the previous article.


Sulfur, air and water out

Up to 1,000 feet (305 meters) t ti

Rock


Selenium and tellurium are usually found as impurities in deposits of sulfur ores. All three elements are solid at room temperature and also very brittle. Polonium, however, is a product of radioactive decay in certain miner­als, and therefore unstable. The metallic char­acter of the elements also increases from sul­fur to polonium. Sulfur is a yellow nonmetal. Selenium and tellurium show some metallic properties (tellurium has a silvery luster). Polo­nium is similar to lead, being dense and soft with a low melting point.


Sulfur

Sulfur is a solid yellow nonmetal. It is tasteless and odorless. It often occurs in the form of pale crystals. It is also found in coal, crude oil, natural gas, and oil shales. Many minerals con­tain sulfur, the most abundant mineral being pyrite, a compound of sulfur and iron. The United States (especially Louisiana and Texas) is the world's largest producer of sulfur. Other producers include Poland, the Soviet Union, Canada, and Japan.

Sulfur compounds have been found in me­teorites and in interstellar clouds. The atmos­phere of Venus contains sulfur. Some scien­tists believe that the core of Mars also contains sulfur. The human body, as well as plants and animals, all have small amounts of sulfur.

Two methods are widely used to produce sulfur commercially. The Frasch method ex­tracts sulfur out of layers of calcite (a type of mineral containing calcium and carbon) from deep underground. A process called Claus conversion extracts sulfur from natural depos­its of crude oil and raw natural gas.

Almost all sulfur is used in the production of sulfuric acid. Sulfuric acid is dense, oily, col­orless, and very corrosive—one of the strong­est acids known. A molecule of sulfuric acid consists of two atoms of hydrogen, one atom of sulfur, and four atoms of oxygen. Sulfuric acid is probably the world's most important commercial chemical.

Sulfuric acid is made on a large scale for use in the production of fertilizers from phos­phate rock and ammonia. It is used in making dyes, paints, certain medicines, automobile batteries, explosives, paper pulp, and various textiles. Sulfuric acid is used in the refining of petroleum, the making of iron and other met­als, and the production of various industrial chemicals. It is used to make strong deter­gents. It is an excellent dehydrating agent, being able to remove hydrogen and oxygen-the two components of water—from many substances. Sulfuric acid dissolves many met­als to form compounds that have a wide vari­ety of industrial uses.

Sulfur is also used by itself in the manufac­turing of various products. These include fun­gicides, insecticides, some types of explosives, shampoos, photographic chemicals, storage batteries, and rubber. It has wide use in fields as divergent as the making of medicines and the laying of highway surfaces.

When sulfur is burned, it combines with ox­ygen in the air to form sulfur dioxide, a color­less, poisonous gas with a sharp odor. It is found especially in densely populated areas that may also have oil refineries and factories that burn sulfur-containing coal or oil. If dis­solved in water droplets, sulfur dioxide can form acid rain, which is harmful to vegetation and can even kill wildlife and harm buildings. For these reasons, the emission of sulfur diox­ide into the air by industry is regulated by the U.S. government.



Major groups of elements: Sulfur to polonium 53


Solid sulfur / c  
\y / y^v^v J^z^sz^K
Orthorhombic Monoclinic Ring structure of 8 sulfur atoms
Plastic sulfur w \y\yK


Selenium Selenium is a nonmetal that occurs as a dark-red powder or crystal or as a dark-gray shiny rod. It is extracted from metal sulfide ores— particularly those of nickel, lead, and copper. Although classified as a nonmetal, selenium conducts electricity when light shines upon it. This quality makes it useful in devices that use changes in light to produce changes in elec­tric current. These devices include television cameras, certain kinds of copying equipment, and electric eyes. It is also used to harden rub­ber and to give a red color to glass and ceram­ics. Tellurium Tellurium is a semimetal that is usually found in combination with other metals in nature. It is usually obtained as a by-product of copper refining. Tellurium is used in the refining of petroleum, the curing of rubber, and the mak­ing of certain alloys (combinations of metals). It is sometimes used to color glass and ceram­ics. Some tellurium also goes into the making of television screens.

Polonium Polonium is a radioactive metal produced by the radioactive decay of minerals containing uranium and thorium. It occurs naturally in pitchblende, a black mineral often found near silver deposits. Polonium can also be pro­duced artificially. It gradually decays into an isotope (form) of lead. An isotope of polonium is used as a power source in satellites. It is also used to eliminate static electricity in some industries.

Furnace Molten sulfur burned in air to form sulfur dioxide: S ■ 02 » S07

: Absorber i SO:i dissolved m i sulfuric acid to I form oleum: 1 H2S04 * S03 • H2S20

Reactor Hot S02 and air passed over catalyst to form sulfur trioxide 2SO, • CV-2SO,

Concentrated sulfuric acid H2S04


Water H20

Diluter

y Water added to oleum ■to form sulfuric acid: H2S,07 - H20 >2H2SCv


Solid sulfuroccurs in two crystalline forms. Ortho-rhombic sulfur is found at temperatures below 205° F. (96° C). Monoclinic, or needle-shaped sulfur, exists between the above temper­ature and the melting point of sulfur, about 246° F. (119° C). Both forms have a molecular structure consist­ing of a puckered ring of eight sulfur atoms. Mole­cules of plastic sulfur con­sist of long zigzag chains.

Sulfuric acidis probably the most important bulk chemical manufactured in industrial countries. Most is made in stainless steel plants (far left) by the con­tact process. Sulfur dioxide is first obtained by burning sulfur in dry air. It is then ox­idized to sulfur trioxide using air and a vanadium oxide catalyst. The sulfur tri­oxide is absorbed in con­centrated sulfuric acid to give oleum. This is then di­luted with water.


 


Fact entries

Sulfurhas been known since ancient times. It was first classified as an element by the French chemist An-toine Lavoisier (1743-1794) in 1777. The name comes from the Latin sulphurium, mean­ing brimstone. At. no. 16; at. mass 32.06; m.p. 113-120° C; b.p. 444.6° C.


Seleniumwas discovered by the Swedish chemist Jons Berzelius (1779-1848). He named it after Selene, the Creek word for the moon. At. no. 34; at. mass 78.96; m.p. (gray form) 217° C; b.p. 684.9+1° C.


Telluriumwas extracted from Transylvanian ores in 1782 by the Austrian chem­ist Franz Miiller von Reic-henstein (1740-1825). He named it after the Latin tel-lus, meaning earth. At. no. 52; at. mass 127.6; m.p. 449.8° C; b.p. 989.9° C.


Poloniumwas discovered in pitchblende in 1898 by the French scientists Pierre Curie (1859-1906) and Marie Curie (1867-1934). It was named after Poland, Marie Curie's homeland. At. no. 84; at. mass (the most stable iso­tope) 209.


         
   
 
   
 
 

 

    He
SA 7A 4.0026
u_ Ne
18.9984 20.179
s CI Ar
32.06 35.453 39.948
Se Br Kr
78.96 79.904 83.80
Te I Xe
127,6 126.906 131.29
Po At Rn
(209) (210) (222)

The halogens,which make up Group 7A of the periodic table, show a graduation of chemical properties from the highly reactive fluorine to the comparatively un-reactive iodine.


The halogens

Fluorine (F), chlorine (CD, bromine (Br), iodine (1), and astatine (At) are five reactive nonmetals commonly called the halogens. They make up Group 7A of the periodic table. They all have a strong, unpleasant odor. They dissolve poorly in water. Care is necessary in handling them, because they burn skin easily. Fluorine and chlorine are gases. Bromine is a liquid at ordi­nary temperatures. Iodine and astatine are sol­ids.

Halogen means 'salt producer.' Halogens react (combine) with metals to form the salts in the sea. Common table salt, the best example, is sodium chloride, a combination of the metal sodium and the halogen chlorine. In general, the halogens react with most metals and also many nonmetals, producing many useful com­pounds. These range from antiseptics and medicines to antiknock gasoline and hydro­chloric acid.

Fluorine, chlorine, bromine, and iodine are so reactive they do not occur alone in nature. They are always found combined with other elements. Astatine is radioactive. Although small quantities of it exist in uranium ores, al­most every one of its 30 isotopes (forms) are created artificially. They are extremely unstable and are of no practical use.

The halogens are electronegative. They tend to take up extra electrons from other ele­ments. The addition of an extra electron to a halogen atom charges it with negative electric­ity, making the atom into an ion. It is these ions that combine with metals to form salts known as halides. The halogens can even form com­pounds with themselves. These compounds are known as interhalogens.


Fluorine

Fluorine is a greenish-yellow gas under nor­mal conditions. In nature, however, it is always combined with other elements, being found usually in the minerals fluorite (a combination of calcium and fluorine) and cryolite (an alumi­num ore). Fluorine is the most reactive of all el­ements. It combines with other elements more readily than any other chemical element.

Because it is so reactive, fluorine itself is of little use. Not only do most elements react with it, but some organic compounds catch fire in the gas. Fluorine compounds, known as fluorides, are, however, widely used. Some of them are useful in the chemical and petroleum industries. Others can be used to etch glass, particularly in the manufacture of "frosted" electric light bulbs. Fluorides are used in mak­ing an inert plastic that can withstand large dif­ferences in temperature. Fluorides are also used in making coolants for household refrig­erators and propellants for aerosol sprays. Flu­orides are added to toothpastes and drinking water to help reduce tooth decay.

Chlorine

Chlorine is a yellow-green gas that is very strong-smelling and poisonous. It irritates the eyes and throat. In nature, it is most often com­bined with sodium in sodium chloride—com­mon salt. This compound can be found in sea-water, inland salt lakes, and beds of salt rock.

Large quantities of chlorine are used for bleaching textiles and paper and in the manu­facture of bleaching powder and household bleach. Chlorine is used to kill bacteria in the domestic water supply and in swimming pools. It is also used to make weed killers and insecticides, as well as various drugs, dyes, metals, and plastics.


 



Bromine and chlorinecan | both be extracted from sea-water. The process for pro­ducing bromine (leftand below) relies on the fact that chlorine displaces bromine from its salts. Several uses of chlorine employ its ger­micidal properties. It is used in the production of drink­ing water and in the treat­ment of water for swimming pools (right).

Chlorine

Chlorine

Compressor

 





m

Bromine

Bromine is a dense, dark-red liquid that easily vaporizes into a reddish-brown gas that has a strongly irritating odor. In nature, it is usually found in seawater and in brine, combined with either sodium or magnesium. Bromine is used in both agriculture and in the petroleum in­dustry. It is also used to manufacture dyes, sedatives, anesthetics, photographic materials, and fire-retardant chemicals.

Iodine

Iodine is a solid that has a slight metallic luster. It takes the form of grayish-black flakes. In nature, it occurs in brines in a similar state to bromine. It is also highly concentrated in some sea plants. Iodine is used in chemical analysis. It goes into the preparation of photo­graphic film, mild antiseptics, germicides, drugs, and dyestuffs. Iodine is also an impor­tant trace element in the human body. It is nec­essary in the control of the body's rate of phys­ical and mental development. Without it, the thyroid gland in the neck swells in a condition known as goiter.


*


jHP^


Major groups of elements: The halogens 55


Date: 2015-12-11; view: 221


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